Product ID:GENETRON HP80 (R402A)
MSDS Date:10/01/1994
FSC:6830
NIIN:00N063147
MSDS Number: BYWNM

ALLIED SIGNAL INC

101 COLUMBIA RD
MORRISTOWN, NJ 07962
US

Emergency Phone: 201-455-2000

Info Phone: 201-455-4157

Cage: 0LYW2

HONEYWELL INTL INC ENVIRONMENTAL SYSTEMS AND SERVICES

MORRISTOWN, NJ 07962 US

Telephone: 973-455-3922

Cage: 70308

METHANE, CHLORODIFLUORO-; (CHLORODIFLUOROMETHANE) (HCFC-22)

CAS: 75-45-6

RTECS: PA6390000

Fraction By Weight: 38%

OSHA PEL 1000 PPM

ACGIH TLV: 1000 PPM

PENTAFLUOROETHANE (HFC-125)

CAS: 354-33-6

Fraction By Weight: 60%

OSHA PEL N/K

ACGIH TLV: N/K

PROPANE (R-290)

CAS: 74-98-6

RTECS: TX2275000

Fraction By Weight: 2%

OSHA PEL 1000 PPM

ACGIH TLV: ASPHYXIANT

BE AVOIDED. CLOSE VALVE TIGHTLY AFTER USE &

RTECS: 9999999ZZ

GENERAL VICINITY OF ARC WELDING, OPEN FLAMES/HOT

RTECS: 9999999ZZ

FORMATION OF CHLORIDES, FLUORIDES, HCL AND/OR

RTECS: 9999999ZZ

SPILLAGE/LEAKAGE/IF THERE IS PROBABILITY

RTECS: 9999999ZZ

WARNING SIGNS ARE REC FOR AREAS OF PRINCIPAL EXPOS.

RTECS: 9999999ZZ

SHOWER FACILITIES AT CONVENIENT LOCATIONS . FOR TANK

RTECS: 9999999ZZ

GOGGLES AND FULL LENGTH FACESHIELD .

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: OVEREXPOSURE MAY CAUSE
DIZZINESS & LOSS OF CONCENTRATION. AT HIGHER LEVELS, CNS DEPRESSION
& CARDIAC ARRYTHMIA MAY RESULT FROM EXPOSURE. CHRONIC: TESTS AT
50000PPM, HCFC-22 SHOW A STATISTICALLY SIGNIFICANT INCIDENCE OF
SALIVARY GLAND TUMORS. CHLOROFLUOROCARBON MATLS HAVE PRODUCED
SENSITIZATION (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ: OF THE MYOCARDIUM TO EPINEPHRINE IN
LABORATORY ANIMALS & COULD HAVE A SIMILAR EFFECT IN HUMANS.
ADRENOMIMETICS (E.G., EPINEPHRINE) MAY BE CONTRAINDICATED EXCEPT
FOR LIFE-SUSTAINING USES IN H UMANS ACUTELY OR CHRONICALLY EXPOSED
TOCHLOROFLUOROCARBONS .
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:EYES: FLUSH WITH POTABLE WATER FOR AT LEAST 15 MINUTES. SEE
MD . SKIN: FLUSH WITH COPIOUS AMOUNTS OF WATER. SEE MD .
INHALATION: REMOVE TO FRESH AIR. SUPPORT BREATHING (GIVE OXYGEN OR
ARTI FICIAL RESPIRATION) . INGESTION: CALL MD IMMEDIATELY .

Extinguishing Media:USE ANY STANDARD AGENT. CHOOSE THE ONE APPROPRIATE
FOR THE SURROUNDING FIRE (THE MATERIAL ITSELF IS NOT FLAMMABLE).
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED PRESSURE DEMAND SCBA
& FULL PROTECTIVE EQUIPMENT . USE WATER SPRAY TO KEEP FIRE-EXPOSED
CONTAINERS COOL.
Unusual Fire/Explosion Hazard:CONT W/CERTAIN REACTIVE METALS MAY RSLT
IN FORM OF EXPLO/EXOTHERMIC RXNS UNDER SPECIFIC CNDTNS (E.G., VERY
HIGH TEMPS &/APPROP PRESS). THERMAL DECOMP (SUP DAT)

Spill Release Procedures:ALWAYS WEAR REC PERS PROT EQUIP. EVACUATE ALL
UNPROT PERS. PROT PERS SHOULD REMOVE ANY FLAMES & SHUT OFF LEAK, IF
W/OUT RISK & PROVIDE VENT. UNPROT PERS SHOULD NOT RETURN UNTIL AIR
HAS BEEN TESTED & D ETERMINED SAFE, INCL LOW-LYING AREAS. (SUP DAT)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:ALWAYS WEAR REC PROT EQUIP. AVOID
BRTHG VAPS/LIQ CONT W/EYES, SKIN/CLTHG. DO NOT PUNCTURE/DROP
CYL/EXPOSE THEM TO OPEN FLAME/EXCESSIVE HEAT.
Other Precautions:USE AUTH CYL ONLY. FOLLOW STD SFTY PREC FOR HNDLG &
USE CYL OF COMPRESSED GASES. STORE IN COOL, WELL-VENT AREA OF LOW
FIRE RISK & OUT OF DIRECT SUNLIGHT. PROT CYL & ITS FITTINGS FROM
PHYSICAL DMG. STO R IN SUBSURFACE LOCATIONS SHOULD (ING 4)

Respiratory Protection:NONE GEN REQUIRED FOR ADEQ VENT WORK SITUATIONS.
FOR ACCIDENTAL RELEASE/NON-VENT SITUATIONS, WHERE CONC MAY RISE
>PEL OF 1000PPM, USE NIOSH/MSHA APPRVD SCBA/SUPP AIR RESP. FOR
ESCAPE USE FORMER/NIOSH/ MSHA APPRVD GAS MASK W/ORG VAP CANISTER.
Ventilation:LOC EXHAUST AT FILLING ZONE & AREAS WHERE LEAKAGE PROBABLE.
MECH(GEN) VENT MAY BE ADEQ FOR OTHER OPERATING & STOR AREAS.
Protective Gloves:IMPERVIOUS GLOVES (NEOPRENE).
Eye Protection:ANSI APPROVED CHEMICAL WORKERS (ING 10)
Other Protective Equipment:BECAUSE OF PHYSICAL CHARACT OF MATL, CONT
W/LIQ IS UNLIKELY. IMPERVIOUS BOOTS & CLTHG SHOULD BE USED IN CASE
OF (ING 7)
Work Hygienic Practices:REMOVE & WASH WET CLTHG PROMPTLY. ANY CONTAM
NON-IMPERVIOUS CLTHG SHOULD ALSO BE PROMPTLY REMOVED & WASH BEFORE
REUSE.
Supplemental Safety and Health
VP: 173 PSIA @ 70F; 389.9 PSIA @ 130F. EXPLO HAZ: PRODS MAY INCL
CHLORIDES, FLUORIDES, HCL & PHOSGENE . CNDTNS TO AVOID: WELDING MAY
YIELD TOX &/CORR DECOMP PRODS. MATLS TO AVOID: CALCIUM, POWDE RED
ALUMINUM, MAGNESIUM & ZINC. SPILL PROC: SPILLS & RELEASES MAY HAVE
TO BE REPORTED TO FED &/LOC AUTH.

Boiling Pt:B.P. Text:-57F,-49C
Vapor Pres:SUP DAT
Vapor Density:3.5
Spec Gravity:1.14 (H*2O=1)
pH:NEUT
Evaporation Rate & Reference:>1 (CCL*4=1)
Appearance and Odor:CLEAR COLORLESS LIQUID AND VAPOR, WITH FAINT
ETHEREAL ODOR
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
FRESHLY ABRADED ALUMINUM SURFACES (MAY CAUSE STRONG EXOTHERMIC RXN).
CHEM ACTIVE METALS: SODIUM, POTASSIUM, (SUP DAT)
Stability Condition to Avoid:DO NOT MIX W/OXYGEN/AIR > ATM PRESS. ANY
SOURCE OF HIGH TEMP SUCH AS LIGHTED CIGARETTES, FLAMES, HOT SPOTS,
(SUP DAT)
Hazardous Decomposition Products:HALOGENS, HALOGEN ACIDS, & POSS
CARBONYL HALIDES. THESE ARE TOX & CORR. CHLORIDES, FLUORIDES, HCL,
PHOSGENE .

Waste Disposal Methods:DISP MUST COMPLY W/FEDERAL, STATE, & LOCAL
DISP/DISCHARGE LAWS. DISPOSAL OF WASTE HP80 MAY BE SUBJECT TO
FEDERAL REGULATIONS. USERS SHOULD REVIEW THEIR OPERATIONS, THEN
CONSULT W/APPROPRIATE REGULATOR Y AGENCIES BEFORE DISCHARGING/DISP
OF WASTE.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.